Previous Research

1999 - 2010
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Wheeler, S. E.; McNeil, A. J.; Müller, P.; Swager, T. M.; Houk, K. N.  Probing Substituent Effects in Aryl-Aryl Interactions Using Stereoselective Diels-Alder Cycloadditions. J. Am. Chem. Soc. 2010, 132, 3304-3311.

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Liou, L. R.; McNeil, A. J.; Toombes, G. E. S.; Collum, D. B. Structures of β-Amino Ester Enolates: New Strategies using the Method of Continuous Variation. J. Am. Chem. Soc. 2008, 130, 17334–17341.

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Gruver, J. M.; Liou, L. R.; McNeil, A. J.; Ramírez, A.; Collum, D. B. Solution Structures of Lithium Enolates, Phenolates, Carboxylates, and Alkoxides in the Presence of N,N,N’,N’-Tetramethylethylenediamine: A Prevalence of Cyclic Dimers. J. Org. Chem. 2008, 73, 7743–7747.

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Liou, L. R.; McNeil, A. J.; Ramírez, A.; Toombes, G. E. S.; Gruver, J. M.; Collum, D. B. Lithium Enolates of Simple Ketones: Structure Determination Using the Method of Continuous Variation.  J. Am. Chem. Soc. 2008, 130, 4859–4868.

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Collum, D. B.; McNeil, A. J.; Ramírez, A. Lithium Diisopropylamide: Solution Kinetics and Implications for Organic Synthesis. Angew. Chem. Int. Ed. 2007, 46, 3002–3017.

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McNeil, A. J.; Müller, P.; Whitten, J. E.; Swager, T. M.  Conjugated Polymers in an Arene Sandwich.  J. Am. Chem. Soc. 2006, 128, 12426–12427.

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McNeil, A. J.; Collum, D. B. Reversible Enolization of β-Amino Carboxamides by Lithium Hexamethyldisilazide. J. Am. Chem. Soc.2005, 127, 5655–5661.

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McNeil, A. J.; Toombes, G. E. S.; Gruner, S. M.; Lobkovsky, E.; Collum, D. B.; Chandramouli, S. V.; Vanasse, B. J.; Ayers, T. A. Diastereoselective Alkylation of β-Amino Esters: Structural and Rate Studies Reveal Alkylations of Hexameric Lithium Enolates.  J. Am. Chem. Soc. 2004, 126, 16559–16568.

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McNeil, A. J.; Toombes, G. E. S.; Chandramouli, S. V.; Vanasse, B. J.; Ayers, T. A.; O’Brien, M. K.; Lobkovsky, E.; Gruner, S. M.; Marohn, J. A.; Collum, D. B.  Characterization of β-Amino Ester Enolates as Hexamers via 6Li NMR Spectroscopy.  J. Am. Chem. Soc. 2004,126, 5938–5939.

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McNeil, A. J.; Hinkle, R. J.; Rouse, E. A.; Thomas, Q. A.; Thomas, D. B. Vinyl Carbocations: Solution Studies of Alkenyl(aryl)iodonium Triflate Fragmentations.  J. Org. Chem. 2001, 66, 5556–5565.

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Hinkle, R. J.; McNeil, A. J.; Thomas, Q. A.; Andrews, M. N.  Primary Vinyl Cations in Solution: Kinetics and Products of β,β-Disubstituted Alkenyl(aryl)iodonium Triflate Fragmentations.  J. Am. Chem. Soc. 1999, 121, 7437–7438.